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仪器网/ 行业应用/ 解决方案/ 旋转圆盘电极:用电化学方法在控制Pb(II)/PbO2 系统中形

旋转圆盘电极:用电化学方法在控制Pb(II)/PbO2 系统中形

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ABSTRACT :The formation of lead dioxide PbO2, an important corrosion product in drinking water distribution systems with lead-bearing plumbing materials, has been hypothesized to involve Pb(III) intermediates, but their nature and formation mechanisms remain unexplored. This study employed the electrochemical (EC) method of rotating ring disk electrode (RRDE) and quantum chemical (QC) simulations to examine the generation of intermediates produced during the oxidation of Pb(II) to PbO2. RRDE data demonstrate that PbO2 deposition and reduction involves at least two intermediates. One of them is a soluble Pb(III) species that undergoes further transformations to yield
immobilized PbO2 nanoparticles. The formation of this intermediate in EC system is mediated by hydroxyl radicals (OH•),as was evidenced by the suppression of intermediates formation in the presence of the OH• scavenger para-chlorobenzoic acid.QC simulations confirmed that the oxidation of Pb(II) by OH• proceeds via Pb(III) species. These results show that Pb(III)intermediates play an important role in the reactions determining transitions between Pb(II) and Pb(IV) species and could impact lead release in drinking water. 旋转圆盘电极/MSR装置
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