全部评论(2条)
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- zhaoyujiee18 2014-03-16 00:00:00
- 根据元素周期表,记零族元素原子序数,再来判断所求元素
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- 就雀驯费堆趾 2014-03-16 00:00:00
- 。。。需要吗直接记Z外电子层2n平方
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热门问答
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- 谁帮我翻译一下
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2008-03-24 08:56:44
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2017-07-18 21:21:48
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2008-10-25 07:34:06
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2016-06-18 21:21:20
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- 大哥大姐谁帮我翻译一下
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2009-03-04 01:55:50
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2012-11-21 13:35:40
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- 请帮我初步诊断一下好么?
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- Carbonnanomaterialsarenovelmanufacturedmaterials,havingwidespreadpotentialapplications.Adsorptionofhydrophobicorganiccompounds(HOCs)bycarbonnanomaterialsmayenhancetheirto... Carbon nanomaterials are novel manufactured materials, having widespread potential applications. Adsorption of hydrophobic organic compounds (HOCs) by carbon nanomaterials may enhance their toxicity and affect the fate, transformation, and transport of HOCs in the environment. In this research, adsorption of naphthalene, phenanthrene, and pyrene onto six carbon nanomaterials, including fullerenes, single-walled carbon nanotubes , and multiwalled carbon nanotubes was investigated, which is the first systematic study on polycyclic aromatic hydrocarbons (PAHs) sorption by various carbon nanomaterials. All adsorption isotherms were nonlinear and were fitted well by the Polanyi-Manes model (PMM). Through both isotherm modeling and constructing “characteristic curve”, Polanyi theory was useful to describe the adsorption process of PAHs by the carbon nanomaterials. The three fitted parameters (Q0, a, and b) of PMM depended on both PAH properties and the nature of carbon nanomaterials. For different PAHs, adsorption seems to relate with their molecular size, i.e., the larger the molecular size, the lower the adsorbed volume capacity (Q0), but higher a and b values. For different carbon nanomaterials, adsorption seems to relate with their surface area, micropore volume, and the volume ratios of mesopore to micropore. Quantitative relationships between these sorbent properties and the estimated parameters of PMM were obtained. These relationships may represent a first fundamental step toward establishing empirical equations for quantitative prediction of PAH adsorption by carbon nanomaterials and possibly other forms of carbonaceous (geo-) sorbents, and for evaluating their environmental impact. In addition, high adsorption capacity of PAHs by carbon nanotubes may add to their high environmental risks once released to the environment, and result in potential alteration of PAHs fate and bioavailability in the environment. 展开
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