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秃顶奥义,那位高手知道,请详细介绍一下,感激不尽!

yy82626339 2018-12-05 16:32:16 360  浏览
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秃顶奥义,那位高手知道,请详细介绍一下,感激不尽!
 
2018-12-05 16:32:16 360 0
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请高手帮我翻译一下这一段。。。
Carbonnanomaterialsarenovelmanufacturedmaterials,havingwidespreadpotentialapplications.Adsorptionofhydrophobicorganiccompounds(HOCs)bycarbonnanomaterialsmayenhancetheirto... Carbon nanomaterials are novel manufactured materials, having widespread potential applications. Adsorption of hydrophobic organic compounds (HOCs) by carbon nanomaterials may enhance their toxicity and affect the fate, transformation, and transport of HOCs in the environment. In this research, adsorption of naphthalene, phenanthrene, and pyrene onto six carbon nanomaterials, including fullerenes, single-walled carbon nanotubes , and multiwalled carbon nanotubes was investigated, which is the first systematic study on polycyclic aromatic hydrocarbons (PAHs) sorption by various carbon nanomaterials. All adsorption isotherms were nonlinear and were fitted well by the Polanyi-Manes model (PMM). Through both isotherm modeling and constructing “characteristic curve”, Polanyi theory was useful to describe the adsorption process of PAHs by the carbon nanomaterials. The three fitted parameters (Q0, a, and b) of PMM depended on both PAH properties and the nature of carbon nanomaterials. For different PAHs, adsorption seems to relate with their molecular size, i.e., the larger the molecular size, the lower the adsorbed volume capacity (Q0), but higher a and b values. For different carbon nanomaterials, adsorption seems to relate with their surface area, micropore volume, and the volume ratios of mesopore to micropore. Quantitative relationships between these sorbent properties and the estimated parameters of PMM were obtained. These relationships may represent a first fundamental step toward establishing empirical equations for quantitative prediction of PAH adsorption by carbon nanomaterials and possibly other forms of carbonaceous (geo-) sorbents, and for evaluating their environmental impact. In addition, high adsorption capacity of PAHs by carbon nanotubes may add to their high environmental risks once released to the environment, and result in potential alteration of PAHs fate and bioavailability in the environment. 展开
2010-01-13 13:35:43 354 1
请高手帮忙翻译一下 3
2.2.1. Physical and physicochemical characterization The particle size distribution of the Ch-zeolite was determined using a laser diffraction equipment (CILASk 1064) and standard wet sieving (Mesh Tylerk series). Scanning electron mic... 2.2.1. Physical and physicochemical characterization The particle size distribution of the Ch-zeolite was determined using a laser diffraction equipment (CILASk 1064) and standard wet sieving (Mesh Tylerk series). Scanning electron microscopy (SEM-PHILIPSk XL20) was used for photomicrographs as well as to analyse the Ch-zeolite composition (Energy Dispersion X-ray, EDX). The sample was initially placed in a vacuum chamber for coating with a thin layer (few nanometers) of gold (Au). The specific surface area of the material was measured by the methylene blue technique and by nitrogen gas adsorption methods, with the latter also providing information about particle porosity. In the methylene blue adsorption method, aqueous solutions (50 ml) of methylene blue (100 mg l 1) were agitated using an orbital shaker (Marconik) for an hour at room temperature in the presence of different quantities of the Ch-zeolite (0.05–0.3 g). The suspensions were then allowed to settle for 23 h and the resulting supernatants were centrifuged at 5000 rpm before the analysis of the residual methylene blue concentration. Results obtained correspond to averaged values of three different experiments. The specific surface area was evaluated by the Langmuir model, assuming the formation, at high concentrations, of a dye monolayer and 1.08 nm2 molecule 1, for the cross-sectional area (Van den Hul and Lyklema, 1968). The Ch-zeolite specific surface area was evaluated by the nitrogen gas adsorption method, using automated equipment (Autosorb 1-Quantachrome Instrumentsk), employing multipoint BET isotherm adsorption data fitting. Also from these data, the porosity of the material was evaluated through parameters such as volume of total pores (d < 206 nm), surface area and volume of micropores (d < 2 nm; Micropore Analysis Method). Zeta potential measurements for the natural and ammonia loaded zeolite, as a function of medium pH, were determined using a Zeta Plusk equipment (Brookhaven Instruments). Suspensions (0.01% v/v) of the Ch-zeolite, previously sieved below 37 Am (400 Mesh Tylerk), in a 10 3 mol l 1 solution of KNO3 were used and the medium pH was controlled with the addition of HNO3 (pH< 7) and KOH (pH>7), separately. For the Ch-zeolite saturated with ammonia, suspensions of the material were prepared by the same procedure, except that the sample was loaded with 100 mg NH3–N l 1 of ammonia. 展开
2018-11-22 17:49:22 298 0
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