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Interfacial silica nanoparticles stabilize cocontinu
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本文由 美国布鲁克海文仪器公司 整理汇编
2015-03-12 00:00 384阅读次数
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Interfacial silica nanoparticles stabilize cocontinu
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Interfacial silica nanoparticles stabilize cocontinu
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2015-03-12 00:00
标准
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Interfacial silica nanoparticles stabilize cocontinuous polymer blends
- Weinvestigatedtheformationofcocontinuousstructuresinpolymerblends.Thesepolymericbijels(bicontinuousinterfaciallyjammedemulsiongels)werecomposedofpolystyreneoligomer,polybuteneandfluorescenthydrophobicsilicananoparticles.Amicron-sizedcocontinuousmorphologywasstabilizedbyamonolayerofsilicananoparticlesattheinterface.Real-timeobservationofcoalescencedynamicsinco-continuouspolymerblendsstabilizedbyinterfacialparticleswasforthefirsttimeachievedvialaserscanningconfocalmicroscopy.Wedemonstratedthatsuppressionofcoalescencearisesfromcoverageofinterfacesbynanoparticles.Furthermore,bycombiningconfocalmicroscopywithrheology,wecorrelatedtherheologicalresponseofacocontinuousstructurewithitsmorphologychange.Wefoundthattherheologicalbehaviorcanbeattributedtocompetitionbetweeninterfaceshrinkageandparticlenetworkformation.Inaddition,weshowedthataparticlescaffoldismaintainedevenaftertheremixingoftwopolymerphasesabovethespinodalpoint.Finally,wealsodiscusseddifferencesbetweentheshearresponseoftheparticle-stabilizedcocontinuousstructureandnormalcolloidalgels:theformeroneismorefragilethanthelatterundershear.[详细]
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