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Microwave assisted Petasis reactions
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2005-12-06 00:00 526阅读次数
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Microwave assisted Petasis reactions
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Microwave assisted Petasis reactions
- Microwave assisted Petasis reactions[详细]
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2005-12-06 00:00
其它
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- Wehaveusedadesignofexperiments(DOE)approachtooptimiserapidlyasetofmicrowaveassistedconditionsforthePetasisreaction.Theoptimalconditionsinvolvedthemicrowaveheatingofthereactioncomponentsindichloromethane(1Mconcentration)at120℃for10mininafocussedmicrowave(CEMExplorer).TheseconditionsweresuccessfullyappliedtoarangeofPetasisreactionsemployingeitherglyoxylicacidorsalicylaldehydeasthecarbonylcomponentalongwithanumberofaryl/heteroarylboronicacidsandaminecomponents.[详细]
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Microwave-promoted tandem reactions for the synthesi
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Analysis Solid State Chemical Reactions
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Recent Advances in Automatic Continuous Online Monitoring of Polymerization Reactions (ACOMP)
- ACOMPallowscomprehensive,model-independent,nearrealtimemonitoringofmanydifferenttypesofpolymerizationreactions.Itprovidesconversionkinetics,andtheevolutionofaveragemolarmass,intrinsicviscosityandaveragecompositiondistributions(forcopolymers).Here,recentadvancesinACOMPwillbesummarized,dea领withcontinuousreactors,copolymerization,‘living’typereactions(NMP,RAFT,ATRP,ROMP),polyelectrolytes,heterogeneousphasereactions,includingfreeradicalreactionsinemulsions,andpredictivecontrol.Inthecaseofemulsionpolymerization,anewapproachwillbepresentedinwhichtheevolutionofthecharacteristicsofboththesolublephasemonomerconversion,polymermolarmassandintrinsicviscosity-andthedispersedphaseparticlesizearesimultaneouslymonitored.NSFCBET0623531,BoRITRS019B,NASANCC3-946,TIMES,PolyRMC(TulaneCenterforPolymerReactionMonitoringandCharacterization).[详细]
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