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LGR液态水同位素分析仪在PNAS上发表的Zxin文献
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LGR液态水同位素分析仪在PNAS上发表的Zxin文献
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应用文章
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ZG客户在国际期刊上发表的文章16
- ConversionoftheSurfacePropertyofOleicAcidStabilizedSilverNanoparticlesfromHydrophobictoHydrophilicBasedonHost-GuestBindingInteractionMingChen,WenHuaDing,YangKong,andGuoWangDiao*Thispaperdescribesageneralmethodtochangethesurfacepropertyoftheoleicacidstabilizedsilvernanoparticlesandsuccessfultranferringofthesilvernanoparticlesfromtheorganicphaseintotheaqueousphase.Byvigorousshakingofabiphasicmixtureofthesilverorganosolprotectedwitholeicacidandp-sulfonatedcalix[4]arene(pSC4)aqueoussolution,itisbelievedthataninclusioncomplexisformedbetweenoleicacidmoleculesandpSC4,andtheprotectivelayerofthesilvernanoparticlesshiftsfromhydrophobictohydrophilicinnature,whichdrivesthetransferofsilvernanoparticlesfromtheorganicphaseintotheaqueousphase.TheefficiencyofthephasetransfertotheaqueoussolutiondependsontheinitialpSC4concentration.ThepSC4-oleicacidinclusioncomplexstabilizednanoparticlescanbestableforlongperiodsoftimeinaqueousphaseunderambientatmosphericconditions.TheprocedureofphasetransferhasbeenindependentlyverifiedbyUV-vis,transmissionelectronmicroscopy,Fouriertransforminfrared,and1Hnuclearmagneticresonancetechniques.[详细]
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2018-09-10 11:11
产品样册
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ZG客户在国际期刊上发表的文章15
- Themorphologicaleffectsuponenzymaticdegradationofpoly(butylenesuccinate-co-butyleneterephthalate)s(PBST)FaxueLi*,Xin极anXu,JianyongYu,AminCaoInthiswork,theenzymaticdegradationofpoly(butylenesuccinate-co-butyleneterephthalate)(PBST)copolyesterswasstudiedusingthelipasefromPseudomonas(LipasePS).ThebiodegradationbehaviorwasfoundtostronglydependontheoverallimpactsofseveralimportantfactorsastheBTcomonomerstructureandmolarcontent,thermalcharacteristics,morphology,theenzyme-substrate,andsoforth.Further,thebiodegradedresidualfilmsampleswereallowedtobeanalyzedbymeansofgelpermeationchromatography(GPC),protonnuclearmagneticresonance(1HNMR),differentialscanningcalorimeter(DSC),smallangleX-rayscattering(SAXS),andscanningelectronmicroscope(SEM).Ontheexperimentalevidences,anexo-typemechanismofenzymaticchainhydrolysispreferentiallyoccurringintheamorphousregionwassuggestedforthePBSTfilmsamples.[详细]
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2018-09-10 11:11
产品样册
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ZG客户在国际期刊上发表的文章14
- InfluenceofaramidfibermoistureregainduringatmosphericplasmatreatmentonagingoftreatmenteffectsonsurfacewettabilityandbondingstrengthtoepoxyYuRen,ChunxiaWang,YipingQiu*Oneofthemaindifferencesbetweenalow-pressureplasmatreatmentandanatmosphericpressureplasmatreatmentisthatinatmosphere,thesubstratematerialmayabsorbsignificantamountofwaterwhichmaypotentiallyinfluencetheplasmatreatmenteffects.Thispaperinvestigateshowthemoistureabsorbedbyaramidfibersduringtheatmosphericpressureplasmatreatmentinfluencestheagingbehaviorofthemodifiedsurfaces.Kevlar49fiberswithdifferentmoistureregains(MR)(0.5,3.5and5.5%,respectively)aretreatedwithatmosphericpressureplasmajet(APPJ)withheliumasthecarriergasandoxygenasthetreatmentgas.Surfacewettabilityandchemicalcompositions,andinterfacialshearstrengths(IFSS)toepoxyforthearamidfibersinallgroupsaredeterminedusingwatercontactanglemeasurements,X-rayphotoelectronspectroscopy(XPS),andmicro-bondpullouttests,respectively.Immediatelyaftertheplasmatreatment,thetreatedfibershavesubstantiallylowerwatercontactangles,highersurfaceoxygenandnitrogencontents,andlargerIFSStoepoxythanthoseofthecontrolgroup.Attheendof30dayagingperiod,thefiberstreatedwith5.5%moistureregainhadalowerwatercontactangleandmorepolargroupsonthefibersurface,leadingto75%improvementofIFSSoverthecontrolfibers,whilethoseforthe0.5and3.5%moistureregaingroupswereonly30%.[详细]
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2018-09-10 11:11
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ZG客户在国际期刊上发表的文章13
- PolymerplatingonAZ31magnesiumalloysurfaceandfilmevaluationofcorrosionpropertyZhixinKang,JingSang,MingShao,YuanyuanLiThepolymericthinfilmwaspreparedonthesurfaceofAZ31magnesiumalloybypolymerplatingof6-dihexylamino-1,3,5-triazine-2,4-dithiolmonosodium(DHN)inordertomodifyitssurfacefeatureandtoimproveitsanti-corrosiveproperty.Cyclicvoltammetrywasusedtostudytheelectrochemicalreactionandfilmgrowthprocessofpoly(6-dihexylamino-1,3,5-triazine-2,4-dithiol)(PDH)film,andthereactionpeaksforfilmformationandgrowthwereaffirmed.Thepolymericfilmweightwasdeterminedbyelectronicbalanceanditsinsolublefractionintetrahydrofuranwasalsomeasured.Contactanglemeterwasappliedtotestthesurfacewettabilitywithdistilledwaterdropsatambienttemperature.Itwasfoundthatthepolymer-platedAZ31alloyshowedhydrophobicpropertywithitsdistilledwatercontactangleupto117.2.TheperformancepropertyofpolymericthinfilmformedonAZ31surfacewasstudiedbypotentiodynamicpolarizationandelectrochemicalimpedancespectroscopy(EIS)inthecorrosionsolutionof3.5%NaCl.Theelectrochemicalexperimentresultsshowedthatpolymer-platedthinfilmwithhydrophobicandinsulativecharacteristicscouldprovidesurfacemodificationandaneffectiveanti-corrosiveprotectiontomagnesiumalloysubstratecomparedtotheblankone.[详细]
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2018-09-10 11:11
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ZG客户在国际期刊上发表的文章12
- Thephysicalpropertiesofaqueoussolutionofroom-temperatureionicliquidsbasedonimidazolium:DatabaseandevaluationWeiweiLiu,LingyanCheng,YumeiZhang,HuapingWang?,MingfangYuWereportthesystematicstudiesofthephysicalpropertiesofsystemsinvolvingimidazoliumbasedionicliquidsandwater.Themeasurementsofdensityρ,refractiveindexΔn,viscosityη,specificconductanceκandsurfacetensionγweremadeoverthewholeconcentrationrange.TheequivalentconductivityΛmwascalculated.Thephysicalproperti`esofthesolutionschangedwiththechangeofassociationbetweenionicliquidandwater.Thephysicalpropertiesofthesolutionsalsovarywiththealkyllengthonthecationandpolarityofanion.[详细]
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2018-09-10 11:11
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ZG客户在国际期刊上发表的文章11
- Fabricationandinvitrodrugreleasestudyofmicrospheredrugdeliverysystemsbasedonamphiphilicpoly-,-[N-(2-hydroxyethyl)-l-aspartamide]-g-poly(l-lactide)graftcopolymersYu-XiangZhou,Song-LinLi,Hui-LiFu,Si-XueCheng,Xian-ZhengZhang,Ren-XiZhuoBiodegradableamphiphilicgraftcopolymerswithdifferentcompositionsweresynthesizedbygraftingpoly(l-lactide)(PLLA)sequencesontoawater-solublepoly-,-[N-(2-hydroxyethyl)-l-aspartamide](PHEA)backbone.Thecriticalmicelleconcentration(CMC)ofthegraftpolymerswasdeterminedbyfluorescenceprobetechnique.UsingtheMTT(3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazoliumbromide)assay,thegraftpolymerswereprovedtohavelowcytotoxicity.Basedonthespecificphysicochemicalpropertyofthegraftcopolymers,submicronsizedmicrospheredrugdeliverysystemswerepreparedbyaveryconvenient“ultrasonicdispersionmethod”,whichdidnotinvolvetoxicorganicsolvents.Thedrug-loadedmicrosphereshadaregularsphericalshapewithanarrowsizedistribution.Ahydrophobicdrug,prednisoneacetate,wasencapsulatedintopolymericmicrospheresandtheinvitrodrugreleasewasstudied[详细]
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2018-09-10 11:11
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ZG客户在国际期刊上发表的文章10
- pH-AmplifiedExponentialGrowthMultilayers:AFacileMethodtoDevelopHierarchicalMicro-andNanostructuredSurfacesJinhongFu,JianJi,LiyanShen,AlexanderKu¨ller,AxelRosenhahn,JiacongShen,andMichaelGrunze*Wereportadirectmethodtoamplifytheexponentialgrowthofmultilayerssignificantlybythealternatingdepositionofpolyethylenimine(PEI)athighpHandpoly(acrylicacid)(PAA)atlowpH.ThealternatingpHswitchesthedegreeofionizationofthepolyelectrolytesinthemultilayers,whichenhancesthediffusionofPEIintoandoutofthefilmandhenceincreasesthedepositedmasspercycle.ThesynergeticactionofthepH-tunablechargedensityanddiffusivityoftheweakpolyelectrolytesprovidesanewmethodfortheenhancedgrowthofmultilayerswithhierarchalmicroandnanostructuredsurfaces.[详细]
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2018-09-10 11:11
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ZG客户在国际期刊上发表的文章9
- FluorescentFilmSensorforVapor-PhaseNitroaromaticExplosivesviaMonolayerAssemblyofOligo(diphenylsilane)onGlassPlateSurfacesGangHe,GuofangZhang,FengtingLu¨,andYuFang*Afluorescentfilmsensorwaspreparedbychemicalassemblyofoligo(diphenylsilane)sonaglassplatesurfaceandwasusedforthedetectionofnitroaromaticcompounds(NACs)invaporphase.Thisdesigncombinestheadvantagesoffluorescentfilmsbasedonsingle-layerchemistryandthesignalamplificationeffectofconjugatedpolymersandprovidesaneffectivewaytocreatenovelfluorescencesensingfilmsforNACsexplosives.Theadvantageshavebeendemonstratedexperimentallybythesupersensitiveresponseoftheabove-mentionedfilmtothepresenceoftraceamountsofNACsinvaporphase.Furtherexperimentsshowedthatthesensingprocessisreversible,andthecommonlyencounteredinterferingsubstanceshavenointerferencetotheprocess.Fluorescencelifetimemeasurementsrevealedthatthequenchingisstaticinnature.Thesupersensitiveresponse,andthereversibilityandinterferencefreeofthesensingprocess,makethefilmapromisingNACssensor.[详细]
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2018-09-10 11:11
产品样册
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ZG客户在国际期刊上发表的文章8
- RoomTemperatureIonicLiquidBasedPolystyreneNanofiberswithSuperhydrophobicityandConductivityProducedbyElectrospinningXianboLu,JianhuaZhou,YihuaZhao,YongQiu,andJinghongLi*Inthisreport,apolystyrene-ionicliquid(PS-IL)compositenanofiberwassuccessfullyproducedforthefirsttimebyanelectrospinningmethod.TheelectrospuncompositefilmswerecharacterizedbySEM,FTIR,cyclicvoltammetry,watercontactangle(WCA)measurement,andconductivitymeasurement.Thedimension,morphology,conductivity,andhydrophobicityofelectrospunPS-ILcompositefilmcanbeeffectivelycontrolledbyalteringtheexperimentalparametersforelectrospinning,especiallythecontentofILintheoriginalelectrospinningsolution.TheelectrospunPS-ILcompositefilmdisplayedbothsuperhydrophobicityandconductivity,whichmaybeascribedtothemicro-andnanoscalehierarchicalstructuresofthePS-ILcompositefilmandtheintrinsichydrophobicityandconductivityoftheIL(BMIPF6).EntrapmentofILwithinpolymerbyelectrospinningprovidesafacilewaytocreateIL-basednanofibersandcompositefilmandmayfindwidepotentialapplicationsinthefabricationofcontrollableandfunctionalsurface.[详细]
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2018-09-10 11:11
产品样册
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ZG客户在国际期刊上发表的文章7
- SuperhydrophobicPatternedFilmFabricatedfromDNAAssemblyandAgDepositionLingluYang,ShuoBai,DunshenZhu,ZhaohuiYang,MaofengZhang,ZhifengZhang,ErqiangChen,andWeixiaoCao*InthisarticleweobtainedasuperhydrophobicpatternedAgfilmmainlybytwosteps.ThefirststepistofabricateaDNAfilmpatternthroughpoly(dimethyldiallylammoniumchloride)alternatedepositionwithDNAonalatentimagingfilmformedbytheselectiveUVexposureofaphotosensitivediazoresin/poly(acrylicacid)self-assembly(SA)film.ThesecondstepistobuildupthepatternedAgfilmonaDNAfilmpatternwithAgelectrolessdeposition.Aftersurfacemodificationwithn-dodecanethiolthepatternedAgfilm,whichexhibitsobviousmicrostructuresandnanostructures,willpossesssuperhydrophobicpropertiesandthecontactanglecanreachto162°.[详细]
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2018-09-10 11:11
产品样册
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ZG客户在国际期刊上发表的文章6
- Surface,InterfacialandAggregationPropertiesofSulfonicAcid-ContainingGeminiSurfactantswithDifferentSpacerLengthsJipingYang,JianyunXie,GuangmingChen,andXiaochenChenFoursulfonicacid-containinggeminisurfactants9BA-m-9BA(m=2,3,4,6),6,60-(ethane-1,2-diylbis(oxy))bis(3-nonylbenzenesulfonicacid)(9BA-2-9BA),6,60-(propane-1,3-diylbis(oxy))bis(3-nonylbenzenesulfonicacid)(9BA-3-9BA),6,60-(butane-1,4-diylbis(oxy))bis(3-nonylbenzenesulfonicacid)(9BA-4-9BA),and6,60-(hexane-1,6-diylbis(oxy))bis(3-nonylbenzenesulfonicacid)(9BA-6-9BA),weresynthesizedandcharacterizedbyFouriertransforminfrared(FTIR),1HNMR,elementalanalysis,andmeltingtemperaturemeasurements.Theirabilitytolowerthewatersurfacetensionandhexadecane/waterinterfacialtensionwasmeasuredandcorrelatedwiththehydrophobicityandlengthoftheiralkylspacerchain.Theiraggregatesinaqueoussolutionswereinvestigatedusingdynamiclightscatteringandtransmissionelectronmicroscopy.Sphericalvesiclescouldbefoundinaqueoussolutionsoffourgeminisurfactantswithanapparenthydrodynamicradius(Rh)of100nm.Thecriticalmicelleconcentration(cmc)offourgeminisurfactantsevaluatedbysurfacetensionmeasurementswas1orderofmagnitudesmallerthanthatofconventionalsingle-chainsurfactantsodiumdodecylsulfonate(SDS).AndtheirC20,thegeminisurfactantconcentrationrequiredforloweringthesurfacetensionofwaterby20mN/m,wasabout2ordersofmagnitudesmallerthanthatofSDS,showingexcellentefficiencyatreducingthesurfacetensionofwater.Inaddition,thehexadecane/waterinterfacialtensioncouldbelessthan1.0mN/mafterusingpure9BA-m-9BAinwater.Using9BA-6-9BAthehexadecane/waterinterfacialtensionwasreducedto0.21mN/m.[详细]
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2018-09-10 11:11
产品样册
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ZG客户在国际期刊上发表的文章5
- TunablecellmembranemimeticsurfacespreparedwithanovelphospholipidpolymerMingGong,ShanYang,Jia-niMa,Shi-pingZhang,FrancoiseM.Winnik,Yong-kuanGong*Anovelmethodtofabricateandtunecellmembranemimeticsurfaceswasdevelopedbasedontheuseofanamphiphilicrandomcopolymerbearingphosphorylcholine(PC),stearylandcrosslinkabletrimethoxysilylpropylgroupssynthesizedbyfreeradicalcopolymerization.Thepolymerwascoatedonglasscoverslipsbydip-coating.Thecoatedfilmsweretreatedinwaterallowingreorganizationofthesurfacegroupstomimicthestructureofcelloutermembranes.Thisstructurewasfixedbycrosslinkingofthetrimethoxysilylpropylgroupslinkedtothecopolymerchains,asascertainedbydynamiccontactangle(DCA)andattenuatedtotalreflectanceinfraredspectroscopy(ATR-FTIR)measurements.Ourresultsindicatethatthesurfacestructurecanbetunedtoagreatextenttoobtainastableoutermembranemimeticsurface/interface.[详细]
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2018-09-10 11:11
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