Nanocomposites Examples on Compounding

本文由 赛默飞化学分析仪器 整理汇编

2008-06-12 00:00 528阅读次数

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• Nanocomposites Examples on Compounding

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• Examples of Studies

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• Ceramics Compounding of Feed Stock

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• Interfacial polymerization of thin film nanocomposites: A new concept for reverse osmosis membranes

  作者：AlbertoTiraferria,KaiLoonChenb,RajandreaSethia,MenachemElimelechb　　（aDITAGDipartimentodiIngegneriadelTerritorio,dell’AmbienteedelleGeotecnologie,PolitecnicodiTorino,CorsoDucadegliAbruzzi,24,10129,Torino,Italy　　bDepartmentofChemicalEngineering,EnvironmentalEngineeringProgram,YaleUniversity,NewHaven,CT06520-8286,USA）　　摘要：Injectionofnanoscalezero-valentiron（NZVI）ispotentiallyapromisingtechnologyforremediationofcontaminatedgroundwaters.However,theefficiencyofthisprocessissignificantlyhinderedbytherapidaggregationoftheironnanoparticles.Theaimofthisstudywastoenhancethecolloidalstabilityofthenanoparticlesthroughtheadditionofthe“green”polymerguargum.Weevaluatedthepropertiesofguargumanditsinfluenceonthesurfaceproperties,particlesize,aggregation,andsedimentationofironnanoparticles.Commercialironnanoparticlesweredispersedinguargumsolutions,andtheiraggregationandsedimentationbehaviorswerecomparedtothoseofbareironnanoparticlesandcommercialnanoparticlesmodifiedwithabiodegradablepolymer（polyaspartate）.Highperformancesizeexclusionchromatography,chargetitration,andviscosityassessmentshowedthatguargumisahighmolecularweightpolymerwhichisnearlyneutrallycharged,renderingitsuitableforstericstabilizationoftheironnanoparticles.Electrophoreticmobilitymeasurementsdemonstratedtheabilityofguargumtoadsorbonthenanoparticles,formingaslightlynegativelychargedlayer.Dynamiclightscatteringexperimentswereconductedtoestimatetheparticlesizeofthedifferentnanoparticlesuspensionsandtodeterminetheaggregationbehavioratdifferentionicstrengths.Guargumeffectivelyreducedthehydrodynamicradiusofthebarenanoparticlesfrom500nmtolessthan200nmandpreventedaggregationofthenanoparticlesevenatveryhighsaltconcentrations（0.5MNaCland3mMCaCl2）.Sedimentationprofilesofthedifferentnanoparticlesuspensionsconfirmedtheimprovedstabilityoftheironnanoparticlesinthepresenceofguargum.Theresultsstronglysuggestthatguargumcanbeusedtoeffectivelydeliverstabilizedzero-valentironnanoparticlesforremediationofcontaminatedgroundwateraquifers.　　关键词：Zero-valentironnanoparticles;Guargum;Greenpolymers;Aggregation;Stericstabilization;Groundwaterremediation;DLS;Particlesize[详细]

  2018-08-31 10:11

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• Interfacial polymerization of thin film nanocomposites：A new concept for reverse osmosis membranes

  Interfacial polymerization of thin film nanocomposites：A new concept for reverse osmosis membranes[详细]

  2024-09-13 03:21

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